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%  Lecture presentation aid for the textbook:
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%  Laszlo P. Csernai: " Introduction to Relativistic Heavy Ion Collisions"
% (John Wiley and Sons Ltd, Chicester, New York, Brisbane, Toronto, 
%  Singapore, 1994; ISBN - 0-471-93420-8)
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%  Additional Transparencies for Lecture 4a / Chapter 4a (Not in the book)
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\begin{document}

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\vspace*{-1.2cm}
\subsection{Finite QGP volume effects}

\B In HI reactions QGP will have a small volume and lifetime \LT\\
 - dynamics of the phase transition\\
 - finite size of the QGP, have to be studied

\B In a small finite system: coexisting phases around $T_c$ ---\\
- do not separate clearly

\B Fluid dynamical model calculations predict 10 - 50 fm$^3$ of QGP\\
- strong first order phase transition assumed\\
- with a latent heat near to 2 GeV/fm$^3$ (optimistic SPS)

\B Lattice QCD calculations are also using finite volumes!\\
- $T = 1/(N_\tau a) = \beta^{-1}$\\
- $V = (N_\sigma a)^3 $\\
\LT $ L = (N_\sigma / N_\tau) (\hbar c)/T $\\
- e.g. a lattice of $N_\sigma \times N_\tau = 48 \times 16$ \LT
lattice volume
$$
\Omega_{lattice} = L^3 = \left(\frac{N_\sigma (\hbar c)}{N_\tau T_c}\right)^3
\approx 61 {\rm fm}^3 ,
$$ 
- $T_c= 150 $ MeV is assumed \LT

- the energy density of the system fluctuates\\
- converges to the energy density of one of the two phases\\
- the system can jump or change from one energy state to the other\\
- the probability of energy density distribution is strongly peaked

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\vspace*{-0.8cm}

\B Consider a system in a canonical ensemble of volume $\Omega$,\\
- in contact with a heat-reservoir of temperature $T$\\
\LT fluctuations play an essential role\\
- the probability, $P({\bf x})$, of finding the system in a state ${\bf x}$:
\beq
P({\bf x})\sim \exp{(-\beta \cdot F({\bf x}))} \ ,
\eeq{e1}
- $F({\bf x})=f({\bf x}) \cdot \Omega$ is the free-energy of the system\\
- $f({\bf x})$ is the free-energy density\\
- the system is characterized by the energy density, $e$, \LT
- ${\bf x} \equiv e$.  



\B Bag model EOS:\\
- the eq. energy density in hadronic phase:  $e_h$,
- the eq. energy density QGP: $e_q$:
\beq
e_h(T)=\frac{\pi^2}{10 \cdot (\hbar c)^3} \cdot T^4 \ \
{\rm and} \ \
e_q(T)=\frac{\pi^2}{(\hbar c)^3}\cdot (\frac{37}{30} \cdot T^4 + \frac{34}{90} 
\cdot T_c^4)
\eeq{e3}

\B we have to do is to find the free energy curve, $f(e)$\\
- for arbitrary values of $e$\\
- not just in the well known $e_q$ and $e_h$ points:
\beq
f[e_q(T)]=-p_q(T)=-\frac{\pi^2}{90 \cdot (\hbar c)^3} \cdot (37 \cdot T^4 -
34 \cdot T_c^4) \ ,
\eeq{e4}
\beq
f[e_h(T)]=-p_h(T)=-\frac{\pi^2}{30 \cdot (\hbar c)^3} \cdot T^4
\eeq{e5}
 
\B we use a parametrization\\
- emphasizes the strong first order feature of the phase transition\\
- i.e.: ``best case'', and the reality may be less favorable


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\vspace*{-0.2cm}

PARAMETRIZATION OF THE FREE-ENERGY DENSITY
\bigskip

\B Free-energy density curve must have two minima, (in $e_h$, and $e_q$)\\
- must diverge to infinity for $e=0$ and $e\rightarrow \infty$

\setlength{\baselineskip}{10pt}
{\normalsize\sf
The divergence at $e=0$ leads to
vanishing population of the zero energy density state. This is not exactly
true for a finite system but it can be applied to systems of volume 50
fm$^3$ or larger.
}
 
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\B Parametrizing in the neighbourhood of $e_o$ (local maximum)\\
- $e_o$ is $e_q$ and $e_h$\\
\beq
f(e)=f_1+\frac{K_1}{e}+K_2\cdot (e-e_o)+K_3 \cdot (e-e_o)^2 + 
K_4 \cdot (e-e_o)^3
\eeq{e6}

\B Determination of  parameters: $f_1$, $K_1$, $K_2$, $K_3$, $K_4$ and $e_o$\\
1) - From the local maximum $f'(e_o)=0$ \LT 
$ K_2=K_1/e_0^2 \equiv K_1 \cdot B_2. $\\
2) From  $f'(e_h)=f'(e_q)$ we get $K_3$ and $K_4$ in terms of $K_1$ and $e_o$\\
3) Still $\exists$ three undetermined parameters: $f_1$, $K_1$ and $e_o$ \LT\\


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SURFACE FREE-ENERGY OF A HADRONIC DROPLET

\B Energy density profile of a spherical hadronic droplet can be obtained
from:
\beq
-K \cdot \left(\frac{d^2}{dr^2}+\frac{2}{r} \cdot 
\frac{d}{dr}\right) e(r) +
\frac{\partial f}{\partial e}=0 \ ,
\eeq{e10}
- $K$: coefficient of the surface energy term in the free energy\\
- For our parametrization:
\beq
\frac{\partial f}{\partial e}= K_1 \cdot \frac{(e-e_q)(e-e_h)(e-e_o)}
{e^2e_h^2e_q^2e_o^2} \cdot [e(e_qe_h+e_qe_o+e_he_o)+e_qe_he_o] \ .
\eeq{e11}
\B Near $T_c$: $R\rightarrow \infty$ \LT eq. (\ref{e10}) approximated as:
\beq
-K\cdot \frac{d^2e}{dr^2}+\frac{\partial f}{\partial e}=0.
\eeq{e12}
 - Considering the origin as $x\equiv r-R$ \\
 - in the neighbourhood of the surface ($x\rightarrow 0$): 
\beq
\frac{d^2e(x)}{dx^2}+\xi_o^{-2}\cdot e(x)=0,
\eeq{e13}
- $\xi_o^{-2}= K_1 \cdot A_0 /K$\\
- $A_0$ can be calculated using the parametrization of $f(e)$.

\B Thus the droplet profile near the surface is:
\beq
e(x)=\frac{1}{2}\cdot [e_h+e_q+(e_q-e_h)\tanh{(\frac{x}{\xi_o \sqrt{2}})}]
+(e_o-\frac{e_h+e_q}{2})\cdot \exp{(-\frac{x^2}{2\xi_o^2})}
\eeq{e16}


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\B The surface energy of the bubble from:
\beq
\sigma=K\cdot \int_{-\infty}^{\infty}(\frac{de}{dx})^2 dx
\eeq{e17}
with the proposed energy-density profile $e(x)$ (\ref{e16}), we get
\beq
\sigma=\frac{K}{\xi_o}\cdot A_1,
\eeq{e18}
 - $
A_1=\frac{(e_q-e_h)^2}{3\sqrt{2}}+\frac{(e_o-\frac{e_q+e_h}{2})^2 
\sqrt{\pi}}{2}
$
- Using the parameters:
\beqar
  \sigma&=&50\: {\rm MeV/fm}^2 \nonumber\\
  \xi_o&=&3\: {\rm fm} \\
  T_c&=&169\: {\rm MeV} \nonumber
\eeqar{e21}
Thus all parameters are fixed using $\xi_o$ and (\ref{e18}) \LT
\beq
K_1\cdot A_o \cdot A_1 = \frac{\sigma}{\xi_o}
\eeq{e23}

\B The parametrized $f(e)$ can then be calculated numerically.

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RESULTS
\vspace*{17cm}

Fig. 1. {\it 
The parametrized free energy density, $f(e)$, as a function of the
energy density, $e$, for systems of three different temperatures near the
critical temperature, $T_c=169$ MeV.}
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\B The probability of finding the system in a state $e$\\
- for different $\Omega$ volumes is constructed by 
\beq
\frac{P(e)}{P(e_{ref})}=\exp{\left(-\Omega \cdot 
\frac{f(e)-f(e_{ref})}{T}\right)}
\eeq{e28}
- $P(e_{ref})=\max\{P(e)\}$ and $e_{ref}=e_q\ \ ({\rm or} \: \: e_h)$\\
\B\B  10 fm$^3$ QGP (expected at AGS):  not sufficient to see two phases\\
- Even more so, because of the large hadronic shell\\
\B\B SPS energies: 50 fm$^3$ gives already a possibility\\
- if the parameters of the EOS, $\sigma$ and $\xi$, change to the worse\\
\LT  2 separated phases can be observed at RHIC or LHC energies only.
\vspace*{11cm}

Fig. 2. {\it The relative probability of finding a state of a given energy
density, $e$, in a system of given volume, $\Omega=10, 50$ fm$^3$, 
at a constant temperature, $T=T_c$.}
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